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Electronic Properties and Reactivity of an Isolable Phosphagermaheterocyclic Carbene

✍ Scribed by Dr. Dumitru Ghereg; Sonia Ladeira; Dr. Nathalie Saffon; Dr. Jean Escudié; Prof. Dr. Heinz Gornitzka

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
369 KB
Volume
123
Category
Article
ISSN
0044-8249

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✍ Dr. Dumitru Ghereg; Sonia Ladeira; Dr. Nathalie Saffon; Dr. Jean Escudié; Prof.  📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 347 KB 👁 2 views

We are grateful to the Agence Nationale pour la Recherche (contract ANR-08-BLAN-0105-01) and PhoSciNet (CM0802) for financial support.

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Electronic and structural properties of three protonated forms HFl , ox q Ž . q Ž .x H Fl N , and H Fl N of lumiflavin have been determined at the HFr3-21G level 2 ox 5 2 ox 1 of approximation. Larger delocalization and basicity explain the favorable protonation of N with respect to N whereas N prot