A calculation of the potentialcnergy curves of some electronic states of Naz and Naf is re orted. The crossing of Na; X 'Xi and Naz ' Yg('P-'P) supports the postulated laser-induced reaction Na 2P + Na P P + Nag + e-.
Electronic energy transfer between the high-lying states of Na2
โ Scribed by L.S. Ma; Y.L. Pan; L.E. Ding; C.N. Jiang
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 417 KB
- Volume
- 187
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The collisional energy-transfer process from the 2 'II, to the C 'HU state of Naz has been studied using two-photon excitation in the 630-650 nm range and fluorescence observation of the C 'IT-X 'Z: band. The relative vibrational population distribution of the C 'II. state is similar to a Gaussian function centered on a particular vibrational level and with a narrow width. The fluorescence spectra have been calculated and are in agreement with experimental results,
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