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Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

✍ Scribed by Marcial Moreno-Mañas; Jordi Ribas

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
240 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

S~~~WZY: A high regioselectivity has been observed in the palladia catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6methyl-2pyrone) when both allylic termini have the same steric requirements and different electronic features.

The palladium catalyzed allylation of proton active substrates is a powerful method of carbon-carbon bond formation. ls2 A conanon mechanistic feature for nucleophiles

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