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Electronic effects of bridgehead alkyl substituents: adamantan-1-yl and bicyclo[2,2,2]octan-1-yl

✍ Scribed by Broxton, T. J.; Capper, G.; Deady, L. W.; Lenko, A.; Topsom, R. D.

Book ID: 121480124
Publisher: Royal Society of Chemistry
Year: 1972
Tongue: English
Weight: 570 KB
Volume: 9
Category: Article
ISSN: 1472-779X
DOI: 10.1039/P29720001237

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## Abstract 4‐Substituted bicyclo [2.2.2] oct‐1‐yl radicals were generated by bromine atom abstraction from the corresponding 1‐bromobicyclo [2.2.2] octanes and observed in solution by EPR spectroscopy. A tendency towards lower __a__(H~β~) and __a__(H~γ~) values for inductively electron‐withdrawing

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