At 25OC aryl migrations from negatively-charged pentacoordinate silicon correlate with the abilities of the rearranging groups to bear negative charge, but at lower temperatures the migrations become less dependent on electron-withdrawing stabilization. Substituted (halomethyl)dimethylsilanes (1, Eq
Electronic Effects and the Stereochemistries in Rearrangement−Displacement Reactions of Triaryl(halomethyl)silanes with Fluoride and with Alkoxide Ions
✍ Scribed by Allen, John M.; Aprahamian, Steve L.; Sans, Esther A.; Shechter, Harold
- Book ID
- 120814852
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 192 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3263
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