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Electronic delocalization in NC and NN bonds

✍ Scribed by M. Brémond; G. J. Martin; G. A. Webb; D. J. Reynolds

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
724 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

For a series of compounds with N-C or N-N bonds, the CNDO/S parameterized calculations for Q", the electronic charge density on the nitrogen atom, and m bond orders P" provide evidence for the simultaneous dependence of the -N chemical shift on both of these parameters. The multilinear regressions obtained produce high values for the regression coefficients. The results throw some light on the nitrogen lone pair delocalization mechanism.

📜 SIMILAR VOLUMES

Application of 13C and 15N spectroscopy
Application of 13C and 15N spectroscopy to the study of electronic delocalization in NN bonds: Nitrosamines, hydrazones, triazenes and related protonated species
✍ J. P. Gouesnard; G. J. Martin 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 755 KB

## Abstract ^13^C and ^15^N spectroscopies at natural abundance have been applied to the study of nitrogen lone‐pair delocalization in NN containing compounds: nitrosamines, nitramines, hydrazines, hydrazones and triazenes. Structure‐chemical shift correlations have been derived for nitrosamines;