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Electronic Control of Chiral Quaternary Center Creation in the Intramolecular Asymmetric Heck Reaction

✍ Scribed by Busacca, Carl A.; Grossbach, Danja; Campbell, Scot J.; Dong, Yong; Eriksson, Magnus C.; Harris, Robert E.; Jones, Paul-James; Kim, Ji-Young; Lorenz, Jon C.; McKellop, Keith B.; O'Brien, Erin M.; Qiu, Fenghe; Simpson, Robert D.; Smith, Lana; So, Regina C.; Spinelli, Earl M.; Vitous, Jana; Zavattaro, Chiara

Book ID
127196817
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
262 KB
Volume
69
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Catalytic Asymmetri
ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction: Synthetic Developments and Mechanistic Studies
✍ Atsuyuki Ashimori; Larry E. Overman πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 27 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Asymmetric induction in the creation of
Asymmetric induction in the creation of tri- and tetra-substituted carbon stereocentres by the intramolecular heck reaction
✍ Ronald Grigg; M.J.R. Dorrity; J.F. Malone; Theeravat Mongkolaussavaratana; W.D.J πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 119 KB

A preliminary survey of the use of aminoethers as chiral auxiliaries, in combination with both chiral and achiral phosphines, for palladium catalysed cyclisations is reported. A 55% d.e. was observed for a process creating a tetrasubstituted carbon centre and >95% d.e. for a process creating a trisu