Electronic aspects of enzymatic catalysi
β
Ricardo Ferreira; Marcelo A. F. Gomes
π
Article
π
1982
π
John Wiley and Sons
π
English
β 510 KB
## Abstract Enzymes are large aperiodic structures and this hinders both __ab initio__ molecular orbital and Blochβtype band theory of calculations. A frontier orbital perturbation theory of catalysis is applied to enzymes. Reasons are given for proposing that the inducedβfit conformational changes