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Electronic and steric effects on the stereoselectivity of cyclopropanation reactions catalysed by rhodium meso-tetraphenylporphyrins

✍ Scribed by Pietro Tagliatesta; Alessandra Pastorini


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
100 KB
Volume
185
Category
Article
ISSN
1381-1169

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A series of Mn III porphyrins progressively halogenated in the electrophilic pathway of addition and a stereospecific pathway of oxygen insertion, the former being disfavoured Ξ²-pyrrolic positions was employed to catalyse the epoxidation of cis-stilbene by iodosylbenzene, and to study by electron-wi