Electronic Effects on the Stereoselectiv
β
Enrico Baciocchi; Tristano Boschi; Luigi Cassioli; Carlo Galli; Laurent Jaquinod
π
Article
π
1999
π
John Wiley and Sons
π
English
β 286 KB
A series of Mn III porphyrins progressively halogenated in the electrophilic pathway of addition and a stereospecific pathway of oxygen insertion, the former being disfavoured Ξ²-pyrrolic positions was employed to catalyse the epoxidation of cis-stilbene by iodosylbenzene, and to study by electron-wi