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Electronic and solvent effects on kinetics of SNAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole in MeOH–Me2SO mixtures of varying composition: one reaction with two mechanistic pathways

✍ Scribed by Nizar El Guesmi, Guillaume Berionni…

Book ID
120919825
Publisher
Springer Vienna
Year
2013
Tongue
English
Weight
575 KB
Volume
144
Category
Article
ISSN
0026-9247

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High Br�nsted ?nuc values in SNAr displa
High Br�nsted ?nuc values in SNAr displacement. An indicator of the SET pathway?Electronic supplementary information (ESI) available: first-order rate constants for the reactions of NBD-Cl (Table S1) and NBD-Im+ (Table S2) with p-X-substituted anilines and figures showing the influence of the oxidation potential on the rates of reaction of NBD-Im+ with 1b?e and 1f in 70?30 (Fig. S1) and 20?80 (Fig. S2) (v/v) H2O?Me2SO. See http://www.rsc.org/suppdata/ob/b3/b301031g/
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