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Electronic and Molecular Structures of Pentaammineruthenium Pyridine and Benzonitrile Complexes as a Function of Oxidation State

✍ Scribed by Shin, Yeung-gyo K.; Szalda, David J.; Brunschwig, Bruce S.; Creutz, Carol; Sutin, Norman

Book ID
126851759
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
257 KB
Volume
36
Category
Article
ISSN
0020-1669

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## Abstract The dithiosalicylidenediamine Ni^II^ complexes [Ni(L)] (R=__t__Bu, R′=CH~2~C(CH~3~)~2~CH~2~ 1, R′=C~6~H~4~ 2; R=H, R′=CH~2~C(CH~3~)~2~CH~2~ 3, R′=C~6~H~4~ 4) have been prepared by transmetallation of the tetrahedral complexes [Zn(L)] (R=__t__Bu, R′=CH~2~C(CH~3~)~2~CH~2~ 7, R′=C~6~H~4~ 8