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Electronic and Molecular Structure of High-Spin d 4 Complexes: Experimental and Theoretical Study of the [Cr(D 2 O) 6 ] 2+ Cation in Tutton's Salts

✍ Scribed by Dobe, Christopher; Noble, Christopher; Carver, Graham; Tregenna-Piggott, Philip L. W.; McIntyre, Garry J.; Barra, Anne-Laure; Neels, Antonia; Janssen, Stefan; Juranyi, Fanni


Book ID
120000018
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
484 KB
Volume
126
Category
Article
ISSN
0002-7863

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Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com