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Electronic and infrared spectra of C+60 and C−60 in neon and argon matrices

✍ Scribed by Jan Fulara; Michael Jakobi; John P. Maier

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
605 KB
Volume
211
Category
Article
ISSN
0009-2614

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✦ Synopsis

The electronic transitions of C& and C& isolated iu 5 K neon matrices were detected with well-resolved vibrational structure after NeI irradiation of CW during deposition. On the basis of a C& spectrum obtained by growing a matrix with a mass-selected C& ion beam, overlapping peaks in the electronic spectra were assigned to either C& or C,. The vibrational frequencies 1406 and 1332 cm-' for C&,, and 1386 and 1202 cm-' for C&, were identified in a neon matrix from the infrared spectrum. Cs was also detected after codepositing Na and K with Cm, without irradiation. Relevance of the data to interstellar observations is

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