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Electronic absorption spectra and structure of the benzyl cation and anion

✍ Scribed by N. E. Kruglyak; Yu. A. Kruglyak


Book ID
112363645
Publisher
Springer
Year
1975
Tongue
English
Weight
499 KB
Volume
9
Category
Article
ISSN
0040-5760

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The planar cis conformer is calculated as lowest in energy but the trans is sufficiently close that both species may be present at room temperature. The difference in the peak absorption energy for the strong 1 'A'+2 'A' transition is calculated to be sufflciently large between the conformers to dis