Electronegativity scheme for reactions involving radical addition to vinyl monomers
β Scribed by A. V. Sokolov
- Book ID
- 112424056
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 477 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Relative Arrhenius parameters have been determined for the addition of trifluoromethyl radicals to vinyl chloride (X=CI), vinyl bromide (X=Br), acrylonitrile (X=CN), methyl vinyl ketone (X=COCH3), Z-methylbut-2-ene, and to iso-butene, taking the rate of addition to ethylene as standard. Addition occ
## Abstract Ab initio molecular orbital calculations have been performed on the transition state for the addition of methyl radical to twelve vinyl monomers using the SV 3β21G basis set. A linear relationship has been found between the calculated energies of activation and previously calculated ene
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