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Electron Tunneling through Oligo-p-xylene Bridges

✍ Scribed by Hanss, David; Wenger, Oliver S.

Book ID
111862075
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
455 KB
Volume
47
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Conformational Effects on Long-Range Ele
Conformational Effects on Long-Range Electron Transfer: Comparison of Oligo-p-phenylene and Oligo-p-xylene Bridges
✍ David Hanss; Oliver S. Wenger πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 518 KB

## Abstract Phototriggered intramolecular electron transfer across variable‐length oligo‐__p__‐phenylene and oligo‐__p__‐xylene bridges was investigated in seven molecules. For both types of bridges, charge transfer rates decrease exponentially with increasing number of spacer units. The distance d

Importance of covalence, conformational
Importance of covalence, conformational effects and tunneling-barrier heights for long-range electron transfer: Insights from dyads with oligo-p-phenylene, oligo-p-xylene and oligo-p-dimethoxybenzene bridges
✍ David Hanss; Mathieu E. Walther; Oliver S. Wenger πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 489 KB

This review reports on our recent studies of phototriggered charge transfer in rigid rod-like donorbridge-acceptor molecules in liquid solution as well as between randomly dispersed electron donors and acceptors in frozen organic glasses. Investigation of the distance dependence of the rates of thes