The electronic states in metallic alkali fullerides, K,C,, and Rb,C,, are studied in detail by cw-and pulsed-ESR. The ESR linewidth associated with conduction electrons varies substantially, depending sensitively on the alkali metals used. It is clearly revealed that the linewidth is homogeneous and
Electron tunneling spectroscopy on poly- and single crystalline Rb3C60
✍ Scribed by P. Jess; S. Behler; M. Bernasconi; V. Thommen-Geiser; H.P. Lang; M. Baenitz; K. Lüders; H.-J. Güntherodt
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 225 KB
- Volume
- 235-240
- Category
- Article
- ISSN
- 0921-4534
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✦ Synopsis
The energy gap A of the superconducting compound RbsCe0 is determined by electron tunneling spectroscopy in high vacuum using a low temperature scanning tunneling microscope. A single crystalline sample shows a significantly larger gap value(A = 7.1 meV) than a polycrystalline sample (A ~ 2-4 meV). This behavior is attributed to larger local variation of stoichiometry in the polycrystalline sample.
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Inelastic electron tunneling spectroscopy is used in the analysis of chemisorbed species of urea and alkylthiourea on the alumina surface using an \(\mathrm{Al}_{2} \mathrm{Al}_{2} \mathrm{O}_{3}-\mathrm{Pb}\) tunnel junction. Tunneling spectra of urea, thiourea, \(N, N^{\prime}\)-dimethylthiourea (