𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Electron transmission spectroscopy and MSXα study of closed-shell and open-shell metallocenes

✍ Scribed by Alberto Modelli; Antonio Foffani; Maurizio Guerra; Derek Jones; Giuseppe Distefano

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
728 KB
Volume
99
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

t ia ToIara di sotto 89.40064 Ozzano Emilin (I30). Jta<v l'he elccrron trJnsrniwion spectra of fcrrocene, chrornoccne and vansdoccne, in tlte O-6 eV energy range:, are presented .utd interpreted with the aid of MS?& caiculrttions. Spin-spin interwtions induce the formation of sizeably split ne&vc sr.n~'~ 1% hen an electron is captured into the empty et&d) orbital of the open-shell chromocenc and vansdocene. 1 _ Introduction After the discovery [I] of the first hydrocarbon derivative of iron. dicyclopcntadienyliron (Cp,Fe), a11 tfw lransition-metal andlogues from V to Ni were synthesised and their strucrurd. electronic and chemi-CJ~ properties were estensivcly studied by experimental .uld thcorctical techniques (see. for example refs. [1, 31 )+ In pxticular,accura~e and comprehensive photoelectron spectroscopy irwesti$ations [-i.S] were de-0 009-~614/83/0000-0000/S 03.00 0 1983 Norm-Holland

📜 SIMILAR VOLUMES

Interaction between closed-shell and ope
Interaction between closed-shell and open-shell molecules. 1H relaxation studies of the hydrogen bond between proton-donor molecules and a nitroxide radical
✍ K. Endo; B. Knuettel; I. Morishima; T. Inubushi; T. Yonezawa 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 504 KB

Pulsed and cw NMR methods have bezn used to investigate the 'H relkation of proton donor molecules hp drogen bonded with the DTBN radial. Frequency dependences of proton relaxation times Tr and T2 were studied with a DTBN solution of CHC.13 by the pulsed NMR method. It is shown that the relaxation m

The Sextic Centrifugal Distortion Terms
The Sextic Centrifugal Distortion Terms for an Open-Shell Complex Consisting of a Diatomic Molecule in a 2S+1Σ Electronic State and a Closed-Shell Partner
✍ Wafaa M. Fawzy; Reham M. Reda 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 137 KB

An effective Hamiltonian for calculating rotational energy levels of an open-shell diatomic molecule, in a 2Sϩ1 ⌺ electronic state, weakly bonded to a closed-shell partner was presented (W. M. Fawzy, J. Mol. Spectrosc. 191, 68 -80 (1998)). The Hamiltonian was given as H ϭ H ev ϩ H rot ϩ H sr ϩ H ss