## Abstract The rate constant of the heterogeneous electron transfer from a platinum electrode to aromatic disulfides is low, whereas the homogeneous electron transfer from suitable aromatic anion radicals is much faster. Anion radicals of such aromatic compounds can thus be generated electrochemic
✦ LIBER ✦
Electron Transfer to Sulfides and Disulfides: Intrinsic Barriers and Relationship between Heterogeneous and Homogeneous Electron-Transfer Kinetics
✍ Scribed by Ana Belèn Meneses; Sabrina Antonello; Maria Carmen Arévalo; Concepcion Carmen González; Jadab Sharma; Andrea N. Wallette; Mark S. Workentin; Flavio Maran
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 215 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0947-6539
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A combined flash photolysis and pulse radiolysis experiment was carried out to produce triplet pyrene (P) molecules in micelles of cetyltrimethylammonium bromide and Brtin the surrounding aqueous medium. The reaction 3Pmie + Bryaq + PA,c + 2 Brwas followed by optical absorption measurements in the 1