Electron-Transfer Reagent Anion Formation via Electrospray Ionization and Collision-Induced Dissociation
β Scribed by Huang, Teng-Yi; Emory, Joshua F.; O'Hair, Richard A. J.; McLuckey, Scott A.
- Book ID
- 126042703
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 113 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0003-2700
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π SIMILAR VOLUMES
Doubly charged molecular anions M2-of fullerenes are formed in the gas phase under chemical ionization conditions with isobutane as the reagent gas. The efficiency of double electron attachment increases with increasing size of the fullerenes: the C& ion is the most abundant doubly charged anion in
## Abstract The isobutane chemical ionization (CI) mass spectra of __cis__β and __trans__β1,4βdi(alkoxymethyl)cyclohexanes, with a tertiary alkoxy group ROH and a primary group Rβ²OH, are identical, and they exhibit exclusive elimination of the alcohol ROH originating from the tertiary alkoxyl. The