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Electron Transfer Reactivity in Matrix-Assisted Laser Desorption/Ionization (MALDI): Ionization Energy, Electron Affinity and Performance of the DCTB Matrix within the Thermochemical Framework

✍ Scribed by Vasil'ev, Yury V.; Khvostenko, Olga G.; Streletskii, Alexey V.; Boltalina, Olga V.; Kotsiris, Sotirios G.; Drewello, Thomas


Book ID
127315557
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
212 KB
Volume
110
Category
Article
ISSN
1089-5639

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Although the ionization/desorption mechanisms in matrix-assisted laser desorption/ionization (MALDI) remain poorly understood, there is a clear difference between the energy absorption processes in the ultraviolet (UV) and infrared (IR) modes of operation. UV-MALDI demands an on-resonance electronic