𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Electron transfer reactions of V(IV) with Cl(I), Br(I) and I(I). A kinetic study

✍ Scribed by P. S. Radhakrishnamurti; C. Janardhana; G. P. Behera; G. K. Mohanty

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
398 KB
Volume
14
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A kinetic study on the oxidation of V(IV) by chloramine‐T (CAT) at pH 6.85 by N‐bromo succinimide (NBS) in aqueous acetic acid–perchloric acid media and by N‐iodo succinimide (NIS) in aqueous perchloric acid medium has been carried out. In all the systems studied the order with respect to the oxidant is unity. NBS and CAT oxidation reactions exhibited Michaelis–Menten type kinetics, and the NIS study indicated unit dependence on [substrate]. Independence on acidity has been observed in the case of CAT and NBS reactions, but NIS reactions exhibited inverse unit dependence on [acid]. Novel solvent influences have been noticed in the case of CAT reactions, but with NIS and NBS reactions retardation in the rate has been observed with an increase in the percentage of acetic acid. Plausible mechanisms consistent with the results have been postulated, and suitable rate laws in consonance with the postulated mechanisms have been derived.

📜 SIMILAR VOLUMES

Kinetic study of the reactions Br + IBr→
Kinetic study of the reactions Br + IBr→I + Br2 and I + Br2→Br + IBr
✍ Y. Bedjanian; G. le Bras; G. Poulet 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 2 views

The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ϩ IBr : I ϩ Br 2 consumption in excess of

Ion–molecule reactions of C60Rh+ with CH
Ion–molecule reactions of C60Rh+ with CH3X, C6H5X(X = Cl, Br, I) and CH2I2
✍ Steven Z. Kan; Young C. Xu; Yong G. Byun; Ben S. Freiser 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 622 KB

## Abstract The gas‐phase ion‐molecule chemistry of exohedrally bound C~60~Rh^+^ with CH~3~X, C~6~H~5~X (X = Cl, Br, and I) and CH~2~I~2~ is studied using Fourier transform ion cyclotron resonance mass spectrometry. Reactions with CH~3~I and CH~2~I~2~ yield the buckminsterfullerene derivatives, C~6

Computational studies on the mechanism a
Computational studies on the mechanism and kinetics of Cl reaction with C2H5I
✍ Xiu-Juan Jia; You-Jun Liu; Jing-Yu Sun; Hao Sun; Fang Wang; Zhong-Min Su; Xiu-Me 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB 👁 2 views

The dual-level direct kinetics method has been used to investigate the multichannel reactions of C(2)H(5)I + Cl. Three hydrogen abstraction channels and one displacement process are found for the title reaction. The calculation indicates that the hydrogen abstraction from -CH(2)- group is the domina

Theoretical study of thermal dissociatio
Theoretical study of thermal dissociation and recombination reactions of XONO2 (X = F, Cl, Br, or I)
✍ M.T. Rayez; M. Destriau 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 530 KB

New evaluations of the dissociation enthalpies Ui of XON02 molecules into XO+NOz (X=F, Cl, Br, I) based upon a literature review and theoretical ab initio (6-3 lG\* for F, Cl and DZP basis from Dunning for Br) and semi-empirical PM3 calculations for the whole series are presented. The main feature i