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Electron-Transfer Properties of the Phenolate Anion Derived from a Vitamin E Model in the Presence of a Strong Base in an Aprotic Medium

โœ Scribed by Ikuo Nakanishi; Kei Ohkubo; Tomonori Kawashima; Keiko Inami; Ken-ichiro Matsumoto; Kiyoshi Fukuhara; Haruhiro Okuda; Masataka Mochizuki; Shunichi Fukuzumi; Toshihiko Ozawa; Kazunori Anzai


Book ID
113631821
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
184 KB
Volume
49
Category
Article
ISSN
0891-5849

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Ring opening in the reaction of diphenyl
โœ Gernot Boche; Michael Marsch ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

The reaction of cyclopropanes like 2,3,4-triphenyl-endo-tricyclo[3.2.1.02'0]octane (la) with base is initiated by proton and not by ele$trov transfer. The facile disrotatory cyclopropyl anion ring opening reaction of 2JR2=CN, M =Ll ) at -75ยฐC does not occur synchronously. 2,3,4-Triphenyl-endo-tricyc