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Electron-transfer photochemistry of di-tert-butyl nitroxide

✍ Scribed by Anderson, David Richard; Keute, Joseph S.; Chapel, Harold L.; Koch, Tad H.

Book ID
126930870
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
392 KB
Volume
101
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Upper excited state photochemistry of di
Upper excited state photochemistry of di-tert-butyl nitroxide
✍ David R. Anderson; Tad H. Koch πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 220 KB

Over the past decade the parsmagnetic compound di-tert-butyl nitroxide (DTBN, 1,) has proved to be an interesting and surprisingly versatile quencher of electronically excited species.

Decomposition of di-tert-butyl nitroxide
Decomposition of di-tert-butyl nitroxide in aqueous solutions
✍ T. CΓ‘ceres; C. UrzΓΊa; E. A. Lissi πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 299 KB

Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac