✦ LIBER ✦
Electron transfer photochemistry of bridged allylcyclopropane systems: novel substitution products via deprotonation
✍ Scribed by Dahui Zhou; Jolene Chou; Heinz D. Roth
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 107 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0894-3230
No coin nor oath required. For personal study only.
✦ Synopsis
The electron transfer photochemistry of three rigid, bridged allylcyclopropane systems, 3-carene (1), tricyclo[4.3.1.0 1,6 ]dec-3-ene (2) and tricyclo[4.4.1.0 1,6 ]undeca-3,8-diene (3), is shown to take an unprecedented course: the major products are novel 'substitution' products, in which a hydrogen at an allylic carbon (C 2 ) of the substrate has been replaced by the p-cyanophenyl group.