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Electron Transfer Photochemistry of a Bridged Norcaradiene: A Mechanistic Probe for Radical Cation Nucleophilic Capture

โœ Scribed by Herbertz, Torsten; Blume, Florian; Roth, Heinz D.


Book ID
118187775
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
215 KB
Volume
120
Category
Article
ISSN
0002-7863

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Electron transfer photochemistry of 7-(s
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The electron transfer photo-sensitized reaction of 7-(spirocyclopropane)quadricyclane (1) with methanol produces two rearranged mono-methanol adducts, 2 and 3, and a bis-methanol adduct, 4. The products reveal that 1 แญน + reacts by stereo-and regiospecific attack of methanol on one trisubstituted cyc