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Electron transfer initiated photocylizations of N-allylpridinium and quinolinium salts

✍ Scribed by Ung Chan Yoon; Suzanne L. Quillen; Patrick S. Mariano; Rosemarie Swanson; Jerome L. Stavinoha; Elliott Bay

Book ID: 104220482
Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 255 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86983-x

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✦ Synopsis

Results from study of the photochemistry of N-allylpyrldrnrum and -quinolrnrum perchlorates demonstrate that intramolecular electron transfer occurs to generate cation dlradical precursors of products contwnrng the tetrahydroindolrzidine moiety. Catalytic hydrogenation of the crude photolysates leads to productron of perhydroindolizidines in synthetically useful yields Our recent photochemical studies have focused on substances containing the rminium lCr,

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