## Abstract **Summary:** Mesoporous silica was used as substrate for the grafting of alkyl halides initiators. The control over the surfaceβinitiated polymerization of styrene and MMA, in terms of molar mass and molar mass distribution, was successfully achieved using an ATRP mechanism. The occurre
Electron-Transfer-Induced Iron-Based Atom Transfer Radical Polymerization of Styrene Derivatives and Copolymerization of Styrene and Methyl Methacrylate
β Scribed by Luo, Rong; Sen, Ayusman
- Book ID
- 121801173
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 601 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
The atom transfer radical polymerization of styrene and methyl methacrylate with FeCl 2 /iminodiacetic acid as the catalyst system in bulk was successfully implemented at 70 and 110 Β°C, respectively. The polymerization was controlled: the molecular weight of the resultant polymer was close to the ca
Atom transfer radical copolymerization of Styrene (St) and N-cyclohexylmaleimide (NCMI) with the CuBr/bipyridine catalyst in anisole, initiated by 1-phenylethyl bromide (1-PEBr) or tetra-(bromomethyl)benzene (TBMB), afforded well-defined copolymers with predetermined molecular weights and low polydi