Electron transfer induced cis-trans isomerization of stilbene. Effect of counterions and the existence of two isomeric stilbene dianions
β Scribed by Ward, T. A.; Levin, G.; Szwarc, M.
- Book ID
- 126757015
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 437 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
THAT CANNOT 'ISOMERIZE INTO A TRtlI'iS FORM Keceived 2 June 1975 A dcrivativc olcis-stilbcnc which cannot be isomcrized into ;I rrurls form may be reduced to the rcspeclive radical anions and dinnions: the disproportionation rate ol thcsc radical anions (log h1-l -' s ) and the respective equilibri
Using spin-unrestricted density functional theory (the VWN Becke-Perdew potential), including broken-symmetry and spin-projection methods, we have obtained the potential-energy curves as a function of the central torsional angle of stilbene in the ground (S0), the first excited triplet (T1), the fir