## Abstract Electron spin resonance (ESR) is a sensitive tool to detect the electronβtransfer processes in some specified systems from the change of the ESR signals. In this paper, the interaction between poly(__N__,__N__βdimethylaniline) (PDMA) and 1,1βdiphenylβ2βpicrylhydrazyl (DPPH) was investig
Electron Transfer in Radicals
β Scribed by Massimo Bietti; Steen Steenken
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 22 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Intermolecular electron transfer ET between the parallel benzene anion radical and neutral benzene is studied at the UHFr4-31G level. It is found Ε½ y1 . that the diabatic activation energy remains almost invariant 14.2 kJ mol when d, the distance between the two parallel benzene rings, is ) 0.45 nm.