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Electron Transfer in Donor–Acceptor Molecules of Substituted Naphtoquinones: Spectral and Redox Properties of Internal Charge Transfer Complexes

✍ Scribed by S. Záliš; J. Fiedler; L. Pospı́šil; N. Fanelli; C. Lanza; L. Lampugnani

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
212 KB
Volume
54
Category
Article
ISSN
0026-265X

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✦ Synopsis

The investigated compounds were substituted naphtoquinones containing aniline moiety separated from the quinoid system by a methylene bridge. The nature of substituents on both donor and acceptor parts influenced the degree of formation of an internal charge transfer complex. Properties of the internal charge transfer interactions were investigated by voltammetry, spectroscopy, and in situ spectroelectrochemistry. Quantum chemical interpretation of experiments is given.

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