✦ LIBER ✦

Electron transfer from resonance valence bond superconductor to reagent in solution

✍ Scribed by L.D. Zusman

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 210 KB
Volume: 200
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)87007-c

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✦ Synopsis

The theory of electron transfer reaction from a superconducting electrode which is described in the framework of the resonance valence bond model to a reagent in solution is developed. It is shown that current-overpotential dependence at the boundary between an electrode and solution should be asymmetrical in contrast to that calculated in the framework of the usual BCS theory of superconductivity. It is also shown that the current between a superconducting electrode and solution should be substantially suppressed in comparison with that calculated for the same electrode in the normal state.

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