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Electron transfer at tetrahedral cobalt(II), part IV: kinetics of silver(I) catalysed chlorate reduction

โœ Scribed by Godwin Adefikayo Ayoko; Johnson Femi Iyun; Ibrahim Fasakari El-Idris


Publisher
Springer
Year
1993
Tongue
English
Weight
331 KB
Volume
18
Category
Article
ISSN
0340-4285

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Electron transfer at tetrahedral cobalt(
โœ Godwin A. Ayoko; John Arabel ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 252 KB

The kinetics and mechanism of the reduction of MnO~ by CoW120~O 6 in aqueous HCIO4 were studied. The reaction follows the rate law: with K, = 2.99 x 10 3tool ~dm 3 andk=2.00+0.02x 103 dm 6 mol-2 s-~ at 25 ~ C. Close agreement between kob~ and ko,~, on the basis of Marcus theory suggest an outersphe