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Electron Transfer and Switching in Rigid [2]Rotaxanes Adsorbed on TiO2 Nanoparticles

โœ Scribed by Dr. Elena Lestini; Dr. Kirill Nikitin; Dr. Jacek K. Stolarczyk; Prof. Donald Fitzmaurice

Book ID
102810237
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
805 KB
Volume
13
Category
Article
ISSN
1439-4235

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โœฆ Synopsis

Scheme 2. Chemical structures of tripodal [2]rotaxanes 1 and 3 and the corresponding axles 2 and 4, model tripodal [2]rotaxane 5 and corresponding axle 6 and V 2 model axle 7 tethered to TiO 2 NPs.

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โœ Kirill Nikitin; Elena Lestini; Jacekโ€…K. Stolarczyk; Helge Mรผller-Bunz; Donald Fi ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 598 KB

## Abstract Translational movement of the macrocycle in two structurally similar bistable [2]rotaxanes, which is induced by a fourโ€step electrochemical process in solution, has been investigated by using a methodology developed in the preceding article (__Chem. Eur. J.__ **2008**, __14__, 1107โ€“1116