Electron transfer and homogeneous redox catalysis on glassy carbon electrodes: Part II. Redox catalysis showing catalyst-substrate interchangeability depending upon pH. The Ti(IV) citrate/NH2OH system in citric acid+trisodium citrate media

Electron transfer and homogeneous redox

Electron transfer and homogeneous redox catalysis on glassy carbon electrode—I. Linear sweep and cyclic voltammetric studies on Ti(IV) oxalate-NH2 OH system in oxalic acid media

✍ M. Noel; P.N. Anantharaman 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 557 KB

The electron transfer rate of titanic oxalate on glassy carbon is found to be slower when compared to the same on Hg electrode. The estimated rate constant using Nicholson's method was found to be 1.2 kO.1 x IO-'ems-' The etkt of pH shows similarity with the reports on Hg electrode. Fractional react