✍ Scribed by Priv.-Doz. Dr. Bernd Speiser
No coin nor oath required. For personal study only.
The subject of an exciting debate—does electron transfer play a role in bimolecular nucleophilic substitution (a)? How would this reaction differ from the classical S~N~2 reaction (b)? A number of research groups have employed electrochemical and computational methods to determine if alternatives exist for one of the best known mechanisms in organic chemistry.
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📜 SIMILAR VOLUMES
## Abstract The reduction of the bicyclic G‐factor endoperoxides G3 and G3Me was studied in __N__,__N__‐dimethylformamide using cyclic voltammetry and convolution analysis. Electron transfer leads to irreversible cleavage of the OO bond. Detailed analysis of the voltammetry curves reveals a non‐li
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract Nucoleaophilic substitution by activated organic anions and single and two electron transfer in ring opening reactions of 4‐membered β‐lactones are described.
## Abstract The effect of nonionic micelles of Triton X‐100 on the oxidative decarboxylation of l‐glutamic acid by chloroaurate(III) complexes has been investigated in acetate buffer medium. The reaction is first order with respect to Au(III), but a complex order with respect to glutamate. H^+^ ion