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Electron-Transfer and Acid−Base Properties of a Two-Electron Oxidized Form of Quaterpyrrole that Acts as Both an Electron Donor and an Acceptor

✍ Scribed by Zhang, Min; E, Wenbo; Ohkubo, Kei; Sanchez-Garcia, David; Yoon, Dae-Wi; Sessler, Jonathan L.; Fukuzumi, Shunichi; Kadish, Karl M.


Book ID
127348680
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
569 KB
Volume
112
Category
Article
ISSN
1089-5639

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The charge transfer complex of 1-Naphthylamine as a donor with p-acceptor picric acid has been studied spectrophotometrically in different solvents at room temperature. The results indicate that the formation of charge transfer complex is high in less polar solvent. The stoichiometry of the complex