✦ LIBER ✦
Electron-transfer activation. Salt effects on the photooxidation of tertiary amines : A useful N-demethylation method
✍ Scribed by J. Santamaria; R. Ouchabane; J. Rigaudy
- Book ID
- 104229452
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 202 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Photooxidation of tertiary methylamines sensitized by electron acceptors like PJO-dicyanoanrhracene is shown to proceed by two distinct ways depending on the presence of added salts. In the absence of added salt both nor and N-formyl compounds were obtained while with added salt the nor-derivative is obtained highly eficiently.