Electron transfer. 127 Intermediate oxidation states in the reduction of chromium(VI) with formate
β Scribed by Swapan K. Chandra; E. Gelerinter; E. S. Gould
- Book ID
- 114996535
- Publisher
- Springer Netherlands
- Year
- 1996
- Tongue
- English
- Weight
- 451 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0922-6168
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Keywords: Cytochrome c / Chromium(v) / Saturation kinetics / Separation of K and k ET / Volume profile / Kinetics The irreversible outer-sphere electron-transfer reaction High-pressure experiments were performed at two different pH values. The kinetic (stopped-flow) and thermodynamic between trans-
The X-ray photoemission core level spectra of TlCr 5 Se 8 and Tl 0 2 Cr 5 Se 8 de5nitely exclude the oxidation of Tl(I) to Tl(III) when Tl is removed using a topotactic redox reaction between TlCr 5 Se 8 and bromine in acetonitrile. Alterations are only observed for the multiplett structure of the C