Electronic control of stereoselectivity.
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Leh-Yeh Hsu; Susan J. Hathaway; Leo A. Paquette
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Article
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1984
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Elsevier Science
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French
β 214 KB
the effect of all, due to the customary greater importance of d,-$, interactions relative to those of the c',-Q1 type. In this event, a metallic species with contracted dT orbitals (i.e., a small metal or one in a high oxidation state) would likely favor top-side bonding (viz., z), whereas one with