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Electron spin resonance studies of spin-labelled polymers: Part 5. Synthesis and characterization of meta-labelled polystyrene

✍ Scribed by A.T. Bullock; G.G. Cameron; P.M. Smith


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
186 KB
Volume
14
Category
Article
ISSN
0032-3861

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✍ A.T. Bullock; J.H. Butterworth; G.G. Cameron πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 379 KB

From an analysis of the widths of the hyperfine lines in the ESR spectrum of a nitroxidelabelled polystyrene in toluene solution, the correlation times for rotational diffusion at three temperatures have been measured. The values agree well with published data from NMR studies of polystyrene in solu

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The adsorption of spin-labelled poly(vinyl acetate) from dilute solutions in ethyl acetate, chloroform and toluene onto three silica adsorbents of different surface silanol contents was studied. The adsorption capacities of the three silica samples, which decreased with decreasing surface silanol co

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Low density polyethylene was spin-labelled with an oxazolidine-N-oxyl group. Correlation times for the motion of the label were calculated both in the slow-motion region and in the motionallynarrowed region. In the latter situation, the central line shape was successfully simulated. A correlation ma