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Electron spin resonance studies of electron addition to 2-chloro- and 2-bromo-2-nitropropane

✍ Scribed by Martyn C.R. Symons; W.Russell Bowman

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
255 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

The products of electron addition to 2-chloro-and 2-bromo-2-nitropropane, which include their radical anions, have been detected by electron spin resonance spectroscopy.

Radical anions of various aliphatic a-substituted nitro compounds have been proposed as reactive intermediates in radical-anion chain substitution reactions (SRN1) (Scheme 1) and other related reactions.1'2'3

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Magnetic and ESR measurements have been performed on several samples of the (Cel\_cGd,)Rh2 series in the interval 0 Z c 2 1. It is found that only those Ce atoms with at least 3nn Gd atoms are magnetic. The cerium sublattice appears to reach the magnetic percolation limit at about c=O.3. Using the l