Electron spin resonance studies of barriers to hindered rotation in acetic acid, acetamide, and peptide radicals
β Scribed by Suryanarayana, D.; Sevilla, M. D.
- Book ID
- 126960117
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 635 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
## Radicals generated in linoleic acid and deuterated linoleic acid have been trapped by the spin trap 2-methyl-2-nitroso-propane & q % i = z = 7 GOOH +N-b (MNP) and identified by electron spin resonance (ESR) and ENDOR spectroscopy. The formation of two distinct secondary alkyl radical adducts (o
## Abstract During UV.βirradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.βspectroscopy. The structures of the radicals point to Ξ±βcleavage, Ξ²βdehalogenati