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Electron spin resonance spectra of radicals related to the intermediates in the oxidation of ascorbic acid. Substituted 2,3,4-trioxopyrrolidine radical anions

✍ Scribed by Kirino, Yutaka; Southwick, Philip L.; Schuler, Robert H.

Book ID: 127193151
Publisher: American Chemical Society
Year: 1974
Tongue: English
Weight: 637 KB
Volume: 96
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00810a006

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## Abstract Radical anions of benzo[2.2]paracyclophane (V) and its 1,2,12,12,14,15,17,18‐octadeuterio derivative (V‐d~8~) in three ethereal solvents (DME, THF and MTHF) and in the temperature range of −90 to −50° have been studied by ESR. and ENDOR. spectroscopy. The resulting hyperfine data provid