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Electron spin resonance spectra and structure of the radical cations of 1,3-dichloropropane and other dichloroalkanes

โœ Scribed by Hasegawa, Akinori; Symons, Martyn C. R.; Shiotani, Masaru

Book ID
120041390
Publisher
Royal Society of Chemistry
Year
1989
Tongue
English
Weight
485 KB
Volume
2
Category
Article
ISSN
1472-779X

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Electron spin resonance and structure of
Electron spin resonance and structure of the radical cation of 3-methylpentane
โœ Kazumi Toriyama; Keichi Nunome; Machio Iwasaki ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 291 KB

TheESR spectrum of the radical cation of 3-methylpentane (3-MP) in CFC12CF2Cl has been obtained. The spectrum is almost identical to that for the 2-methylbutane radical cation. From the spectral analysis it is concluded that 3-MP+ has a GT skeletal conformation and the unpaired electron is confined