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Electron spin resonance measurements of dibenzenechromium cation

✍ Scribed by R. Prins; F.J. Reinders

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
402 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis

ESR spectra of liquid and solid solutions of Cr(C the spectr+a show a well resolved proton hyperfine H6)$ have been measured. Even in solid solution s f ructure which is explained by rotation of the Cr(C6Hd2 cation around its main axis. An analysis of the 62Cr hyperfine coupling constants indicates that the unpaired electron is in the alg (3ds2) orbital. The experimental results agree fairly well with the results of an e.xtended Hilckel MO calculation.

CHEMICAL PHYSICS LETTEPS January 1969

-H

around the x, y peak, so that BCr can be evaluated from this hyperfine structure. In the spectra no indication has been found of the axial 5%.Zr

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