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Electron spin resonance and electrochemical study of thiohydroxamate and 1-phenyl-3-imino-2(1H)-pyridinethione complexes of copper(II)

✍ Scribed by Becher, Jan.; Brockway, David J.; Murray, Keith S.; Newman, Peter J.; Toftlund, Hans.


Book ID
127112652
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
974 KB
Volume
21
Category
Article
ISSN
0020-1669

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Voltammetric studies on mesoionic 1,2,3-oxa-and -thiadiazoles conÐrmed that the former may be reduced irreversibly at potentials between [1.48 and [2.12 V vs. Fc/Fc`in acetonitrile at a scan rate of 200 mV s~1, whereas the latter are reduced reversibly under the same conditions. The corresponding an