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Electron-Spin Polarizations Generated from Interactions between Excited Triplet Porphyrins and Stable Radicals Studied by Time-Resolved Electron Paramagnetic Resonance

โœ Scribed by Fujisawa, Jun-ichi; Ohba, Yasunori; Yamauchi, Seigo


Book ID
118279728
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
212 KB
Volume
101
Category
Article
ISSN
1089-5639

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An electron spin resonance study of the reaction of aliphatic amines and OH-with 4nitroveratrole (NV) in its lowest electronic triplet state is presented. It is concluded that both nucleophiles transfer an electron to triplet-state NV in the first chemical step of the reaction. This is then followed