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Electron-Rich Vaska-Type Complexes trans-[Ir(CO)Cl(2-Ph2PC6H4COOMe)2] and trans-[Ir(CO)Cl(2-Ph2PC6H4OMe)2]: Synthesis, Characterisation and Reactivity

โœ Scribed by Dipak Kumar Dutta; Biswajit Deb; Bhaskar Jyoti Sarmah; J. Derek Woollins; Alexandra M. Z. Slawin; Amy L. Fuller; Rebecca A. M. Randall


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
482 KB
Volume
2011
Category
Article
ISSN
1434-1948

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Aqueous Organometallic Chemistry. Synthe
โœ Gรกbor Papp; Henrietta Horvรกth; รgnes Kathรณ; Ferenc Joรณ ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 98 KB

## Abstract An improved procedure for the preparation of the known H~2~Oโ€soluble hydrogenation and hydroformylation catalyst, [RuH(Cl)(CO)(__m__tppms)~3~] (__m__tppms=__meta__โ€monosulfonated triphenylphosphine) was developed. In contrast to the methods reported earlier, this synthesis yields the co