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Electron paramagnetic resonance studies of component once and cofactor of the vanadium nitrogenase of Azotobacter vinelandII

✍ Scribed by MelindaE. Oliver; BrianJ. Hales

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
94 KB
Volume
36
Category
Article
ISSN
0162-0134

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We follow the initial activation of the nitrogen molecule at the FeMo cofactor of nitrogenase and subsequently model the hydrogenation of N up to the fourth 2 protonation step using the intermediate neglect of differential overlap quantum-chemical model. The results obtained favor a reaction mechani